In ionic materials, the band gap is too large for thermal electron promotion. Cation vacancies allow ionic motion in the direction of an applied electric field, this is referred to as ionic conduction. High temperatures produce more vacancies and higher ionic conductivity. At low temperatures, electrical conduction in insulators is usually along the surface, due to the deposition of moisture that contains impurity ions.
Home
Material Science
Conduction in Ionic Materials
Comments are closed.